Department of Medicinal and Biological Chemistry

Jon R. Kirchhoff, Ph.D.

Photo of Dr. Kirchhoff

Associate Professor

419.530.1515 Phone
Wolfe Hall 2265


B.A., 1979 State University of New York at Cortland
Ph.D., 1985 Purdue University    

Research Interests

Development of modified electrodes and microelectrodes; electrochemical detectors for capillary electrophoresis; bioanalytical chemistry; electrochemical and spectroelectrochemical methods for characterization and analysis; redox properties, photochemistry and photophysics of coordination compounds; synthetic methods for low-valent rhenium complexes.

Publications (selective papers represented)

  1. Okamoto, K.-I., J.R. Kirchhoff, W.R. Heineman, E. Deutsch, and M.J. Heeg. Preparation, characterization, electrochemical properties and single crystal structural analysis of [Tc(SCP)2(DMPE)2](PF6)3. Where SCP is the Zwitter-Ionic ligand SCH2P+(CH3)2(CH2)2P(S)(CH3)2 and Dmpe is l,2bis(dimethylphosphino)ethane. Polyhedron 12: 749-757, 1993.

  2. Kummer, M., and J.R. Kirchhoff. Graphite-coated metal mesh optically-transparent electrodes. Anal Chem. 65: 3720-3725, 1993.

  3. Lee, Y.F., and J.R. Kirchhoff, J.R. Design and characterization of a spectroelectrochemical cell for absorption and luminescence measurements. Anal. Chem. 63: 3430-3434, 1993.

  4. Wittstock, G., H. Emons, M. Kummer, J.R. Kirchhoff, and W.R. Heineman. Application of scanning electrochemical microscopy and scanning electron microscopy for characterization of carbon-spray modified electrodes. Fresenius J. Anal Chem 348: 712-718, 1994.

  5. Lee, Y.F., and J.R. Kirchhoff. Absorption and luminescence spectrochemical characterization of highly luminescent re(II) complex. J. Am. Chem. Soc.116: 3599-3600, 1994.

  6. Giu, Y., H. Lee, J.R. Kirchhoff, L. Manzey, and R.A. Hudson. Mechanism of action of the redox affinity reagent trimethylammoniomethyl catechol. Biochemistry 33: 8486-8494, 1994.

  7. Zhao, G., D.M. Giolando, and J.R. Kirchhoff. Fabrication of silica-coated fiber ultramicroelectrodes by chemical vapor deposition. J. Electroanal. Chem. 379: 505-508, 1994.

  8. Brooks, K.T., D.C. Finnen, J.R. Kirchhoff and A.A. Pinkerton. Bis(triphenylphosphine2,3-bis(2-pyrazine)-copper(I) nitrate. Acta Cryst. C50: 1696-1699, 1994.

  9. Zhao, G., D.M. Giolando, and J.R. Kirchhoff. Carbon ring-disk ultramicroelectrodes. Anal. Chem. 67: 1491-1495, 1995.

  10. Zhang, Z., L.M.V. Tillekeratne, J. R. Kirchhoff and R.A. Hudson. High performance liquid chromatographic separation and pH-dependent electrochemical properties of pyrroloquinoline quinone and three closely related isomeric analogues. Biochem. Biophys. Res. Commun. 212: 41-47, 1995.

  11. Zhao, G., D.M. Giolando and J.R. Kirchhoff. Chemical vapor deposition fabrication and characterization of silica coated carbon fiber ultramicroelectrodes. Anal. Chem. 67: 2592-2598, 1995.

  12. Lee, Y.F, J.R. Kirchhoff, R.M. Berger, and D. Gosztola. Spectroelectrochemistry and excited state absorption spectroscopy of rhenium(I) a,a'-diimine complexes. J. Chem. Soc., Dalton Trans 3677-3682, 1995.

  13. M. Zhong, J. Zhou, S.M. Lunte, G. Shao, D.M. Giolando, and J.R. Kirchhoff. Dual electrode detection for capillary electrophoresis/electrochemistry. Anal. Chem. 68: 203-207, 1996.

  14. Kummer, M., and J.R. Kirchhoff. Electron Transfer Properties of Pyrolytic Graphite optically Transparent Electrodes. Electroanalysis 8: 24-528, 1996.

  15. Kirchhoff, J.R., J.F. Wheeller, C.E. Lunte, W.R. Heineman, S.H. Jenkins. Electrochemistry: Principles and Measurement. In Clinical Chemistry-Theory, Correlation and Analysis, 3rd ed.; Kaplan, L.A., A.j. Pesce, eds; C.V. Mosby Company: St. Louis, MO Chapter 15, 1996.

  16. Shen, R., L.M.V. Tillekeratne, J.R. Kirchhoff and R.A. Hudson. 6-hydroxycatecholine, a choline-mimicking analogue of the selective neurotoxin, 6-hydroxydopamine. Biochem. Biophys. Res. Commun 228: 187-192, 1996.

  17. Meier, F., D.M. Giolando, and J.R. Kirchhoff. Silicon carbide: a new electrode material for voltammetric measurements. J. Chem. Soc. Chem. Commun. 2553-2554, 1996.

  18. Kirchhoff, J.R. Luminescence spectroelectrochemistry. Current Separations 16: 11-14, 1997.

  19. Kirchhoff, J.R., M.R. Allen, B.V. Cheesman, K. Okamoto, W.R. Heineman, E. Deutsch. Electrochemistry and spectroelectrochemistry of [Re(1,2-bis(dimethylphosphino)ethane)3]. Inorg. Chim. Acta. 262: 195-202, 1997.

  20. Burns, F.M., D.M. Giolando, J.R. Kirchhoff. Characterization of ceramic-basedual ultramicroelectrodes by microscopic and electrochemical methods. Microscopy and Microanalysis 3: 12451246, 1997. Abstract.

  21. Kirchhoff and K. Kirschbaum. Comparative x-ray crystallographic characterization of the mono-and bimetallic complexes of rhenium(I) tricarbonyl chloride with 2,3-bis(2-pyridyl) pyrazine. Polyhedron 17: 4033-4039, 1998.

  22. Smith, A.R., Kirchhoff, J.R.; Tillekeratne, L.M.V.; Hudson, R.A. Separation of Negatively Charged Isomeric Quinones by Capillary Electrophoresis with Reductive Electrochemical Detection in Acidic Media. , Anal. Commun., 36, 371-374, 1999.

  23. Smith, A.R.; Kirchhoff, J.R.; Zhang, Z.; Tillekeratne, L.M.V.; Hudson, R.A., J. Separation of the Enzyme Cofactor Pyrroloquinoline Quinone and Three Isomeric Analogues by Capillary Electrophoresis with Ion-Pairing Media., 193-199, 2000.

  24. Mauro, L.S.; Kuhl, D.A.; Kirchhoff, J.R.; Mauro, V.F.; Hamilton, R., Impact of Oral Bases on Aluminum Absorption. American Journal of Therapeutics, in press.

  25. Inoue, T.; Kirchhoff, J.R Electrochemical Detection of Thiols with a Coenzyme Pyrroloquinoline Quinone Modified Electrode., Anal. Chem., submitted.

  26. Bozon, J. P.; Giolando, D.M.; Kirchhoff, J.R Development of Metal-Based Microelectrode Sensor Platforms by Chemical Vapor Deposition. ., J. Electroanal. Chem., submitted.

  27. Hudson, R.A., and Kirchhoff, J.R. Quinone Cofactors Analytical Biochemistry, invited review.
Last Updated: 6/26/15