Connect with Students or Anyone on MSN
Now you can use the Microsoft Office Communicator client to chat with people who use Microsoft based Instant Messaging accounts. These include Hotmail, MSN, Live.com and even Rockets.utoledo.edu. To add a Microsoft client, To begin, just add a new contact using the "Tools" menu in your Microsoft Office Communicator client. To access the tool menu click the arrow in the top left hand corner.
Move your mouse over tools and then click add a contact.
Then add the contacts email address and you can start instant messaging all your friends on MSN or Live.