Department of Chemistry and Biochemistry

Dr. Schmidt's publications

Behrle, A. C.; Schmidt, J. A. R. “Synthesis and Reactivity of Homoleptic α-Metalated N,N-Dimethylbbenzylamine Rare-Earth-Metal Complexes.” Organometallics, 2011, 30, 3915-3918.

 

Kuchenbeiser, G.; Shaffer, A. R.; Zingales, N. C.; Beck, J. F.; Schmidt, J. A. R. “Palladium(II) 3-Iminophosphine (3IP) Complexes: Active Precatalysts for the Intermolecular Hydroamination of 1,2-Dienes (Allenes) and 1,3-Dienes with Aliphatic Amines under Mild Conditions.” J. Organomet. Chem., 2011, 696, 179-187. (Invited Contribution)

 

Neshat, A.; Schmidt, J. A. R. “Derivatization of Niobium Complexes Bearing Imido and Acetophenone Imine Ligands.” Organometallics, 2010, 29, 6219-6229.

 

Beck, J. F.; Neshat, A.; Schmidt, J. A. R. “Structural Characterization of Novel ortho-Lithiated Imines.” Eur. J. Inorg. Chem., 2010, 5146-5155.

 

Hertel, M. P.; Behrle, A. C.; Williams, S. A.; Schmidt, J. A. R.; Fantini, J. L. “Synthesis of Amine, Halide, and Pyridinium Terminated 2-Alkyl-p-tert-butylcalix[4]arenes.” Tetrahedron, 2009, 65, 8657-8667.

 

Beck, J. F.; Baiz, T. I.; Neshat, A.; Schmidt, J. A. R. “Titanium Imido Complexes Utilizing Orthometallated Derivatized Acetophenone and Piperonal Imine Ligands: Synthesis, Isolation and Characterization.” Dalton Trans., 2009, 5001-5008.

 

Neshat, A.; Seambos, C. L.; Beck, J. F.; Schmidt, J. A. R. “Mono-Anionic Acetophenone Imine Ligands: Synthesis, Ortho-Lithiation, and First Examples of Group (V) Metal Complexes.” Dalton Trans., 2009, 4987-5000.

 

Shaffer, A. R.; Schmidt, J. A. R. “Reactivity of (3-Iminophosphine)palladium(II) Complexes: Evidence of Hemilability.” Organometallics, 2009, 28, 2494-2504.

 

Shaffer, A. R.; Schmidt, J. A. R. “A Versatile Methodology for the Synthesis of α,β-Unsaturated 3-Iminophosphines.” Chem.-Eur. J., 2009, 15, 2662-2673.

 

Shaffer, A. R.; Schmidt, J. A. R. “Palladium(II) 3-Iminophosphine Complexes as Intermolecular Hydroamination Catalysts for the Formation of Imines and Enamines.” Organometallics 2008, 27, 1259-1266.

 

Baiz, T. I.; Schmidt, J. A. R. “A Discrete Ortholithiated Acetophenone Imine Derivative: Isolation, Characterization, and Synthesis of Group IV Metal Complexes.” Organometallics 2007, 26, 4094-4097.

 

Anderson, L. L.; Schmidt, J. A. R.; Arnold, J.; Bergman, R. G. “Neutral and Cationic Alkyl Tantalum Imido Complexes: Synthesis and Migratory Insertion Reactions.” Organometallics 2006, 25, 3394-3406.

 

Schmidt, J. A. R.; Lobkovsky, E. B.; Coates, G. W. “Chromium(III) Octaethylporphyrinato Tetracarbonylcobaltate: A Highly Active, Selective, and Versatile Catalyst for Epoxide Carbonylation.” J. Am. Chem. Soc. 2005, 127, 11426-11435.

 

Cui, C.; Shafir, A.; Schmidt, J. A. R.; Oliver, A. G.; Arnold, J. “Synthesis and Characterization of Mono b-Diketiminatosamarium Amides and Hydrocarbyls.” Dalton Trans. 2005, 1387-1393.

 

Getzler, Y. D. Y. L.; Schmidt, J. A. R.; Coates, G. W. “Synthesis of an Epoxide Carbonylation Catalyst: Exploration of Contemporary Chemistry for Advanced Undergraduates.” J. Chem. Educ. 2005, 82, 621-624.

 

Schmidt, J. A. R.; Mahadevan, V.; Getzler, Y. D. Y. L.; Coates, G. W. “A Readily Synthesized and Highly Active Epoxide Carbonylation Catalyst Based on a Chromium Porphyrin Framework: Expanding the Range of Available b-Lactones.” Org. Let. 2004, 6, 373-376.

 

Cui, C.; Giesbrecht, G. R.; Schmidt, J. A. R.; Arnold, J. “A Cationic Aluminum Methyl Complex Supported by an Anionic Tacn Ligand.” Inorg. Chim. Acta 2003, 351, 404-408.

 

Schmidt, J. A. R.; Giesbrecht, G. R.; Cui, C.; Arnold, J. “Anionic Triazacyclononanes: New Supporting Ligands in Main Group and Transition Metal Organometallic Chemistry.” Chem. Commun. 2003, 1025-1033.

 

Schmidt, J. A. R.; Arnold, J. “First-Row Transition Metal Complexes of Sterically-Hindered Amidinates.” Dalton Trans. 2002, 3454-3461.

 

Giesbrecht, G. R.; Cui C.; Shafir, A.; Schmidt, J. A. R.; Arnold, J. “Divalent Lanthanide Metal Complexes of a Triazacyclononane-Functionalized Tetramethylcyclopentadienyl Ligand: X-Ray Crystal Structures of [C5Me4SiMe2(iPr2-tacn)]LnI (Ln = Sm, Yb; tacn = 1,4-diisopropyl-1,4,7-triazacyclononane).” Organometallics 2002, 21, 3841-3844.

 

Arnold, J.; Knapp, V.; Schmidt, J. A. R.; Shafir, A. “Reactions of N,N’,N’’-trimethyl-1,4,7-triazacyclononane with Butyllithium Reagents.” Dalton Trans. 2002, 3273-3274.

 

Cui, C.; Schmidt, J. A. R.; Arnold, J. “An Unsolvated Lithium Trihydroaluminate and the Corresponding Trialkynylaluminates Supported by an Anionic Triazacyclononane Ligand.” Dalton Trans. 2002, 2992-2994.

 

Schmidt, J. A. R., Arnold, J. “Reactions of a Triazacyclononane-Supported Tantalum-Lithium Bridging Alkylidene with Organic Substrates.” Organometallics 2002, 21, 3426-3433.

 

Schmidt, J. A. R., Arnold, J. “Synthesis and Characterization of a Series of Sterically-Hindered Amidines and their Lithium and Magnesium Complexes.” Dalton Trans. 2002, 2890-2899.

 

Schmidt, J. A. R.; Arnold, J. “Neutral and Cationic Aluminum Complexes Supported by Sterically-Bulky Amidinate Ligands.” Organometallics 2002, 21, 2306-2313.

 

Schmidt, J. A. R.; Arnold, J. “Reactivity of a Tantalum-Lithium Alkylidene Supported by an Anionic Triazacyclononane Ligand.” J. Am. Chem. Soc. 2001, 123, 8424-8425.

 

Schmidt, J. A. R.; Chmura, S. A.; Arnold, J. “Alkyl and Alkylidene Tantalum-Lithium Complexes Supported by an Anionic Triazacyclononane Ligand.” Organometallics 2001, 20, 1062-1064.

 

Gebauer, A.; Schmidt, J. A. R.; Arnold, J. “Synthesis, Characterization, and Properties of a Lithium 21-thiaporphyrin Complex.” Inorg. Chem. 2000, 39, 3424-3427.

 

Schmidt, J. A. R.; Arnold, J. “Mono-Amidinate Complexes Stabilized by a New Sterically-Hindered Amidine.” Chem. Commun. 1999, 2149-2150.

 

Freitas, M. A.; O’Hair, R. A. J.; Schmidt, J. A. R.; Tichy, S. E.; Plashko, B. E.; Williams, T. D. “Gas-Phase Reactions of Glycine, Alanine, Valine and Their N-methyl Derivatives with the Nitrosonium Ion, NO+.” J. Mass. Spectrom. 1996, 31, 1086-1092.

 

O’Hair, R. A. J.; Freitas, M. A.; Schmidt, J. A. R.; Hatley, M. E. “Gas-Phase Methylation of the 2-hydroxypyridine 2-pyridone System by the Dimethylchlorinium Ion.” Eur. Mass Spectrom. 1995, 1, 457-463.

 

O’Hair, R. A. J.; Freitas, M. A.; Gronert, S.; Schmidt, J. A. R.; Williams, T. D. “Concerning the Regioselectivity of Gas-Phase Reactions of Glycine with Electrophiles – The Cases of the Dimethylchlorinium Ion and the Methoxymethyl Cation.” J. Org. Chem. 1995, 60, 1990-1998.
Last Updated: 6/26/15